Hot For Teacher-EVH: Perfect representation of his style sans tapping. i.e. primarily a rhythmic guitar player with a sometimes-jazzy sense of timing.
Molto Arpeggiosa-Yngwie Malmsteen: Just check out that opening lick from Yngwie. Brilliant.
Splendido Sundance-Al Di Meola: I suppose not really rock, but still just an awesome piece for two guitars.
I don't want to hear about it later-EVH: Another really awesome solo (too bad the solo is in the middle of a mediocre song)
Back In Black isn't a song. It's a divine call that gets channeled through five righteous dudes every thousand years or so. That's why dragons and sea monsters don't exist anymore.