As for good places to start. Think of the chord or key your soloing over. i.e. C major. Now think of what notes make up the C major triad, C, E, G. Any 3 of these notes is a good starting point. Try C using the C minor pentatonic over a C major chord. Contrasting but interesting. Think of each scale as a different color of harmony that you can apply to an individual chord or entire key.
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