Zakk Wylde, Live and Loud....if you've seen it you know what i'm talking about. (and there's one from the late 80's where he's only been playing for 5 years, it really pisses you off when you hear it and realize he's only been playing for 5 years lol)
Besides that, Anything John Petrucci plays oh oh oh remember the first time you ever heard the Heartbreaker solo (Zeppelin not Benetar) ? that's always a good one.
"I need a girl who's as hot as my guitar."