For instance, Marty Friedman solos in old megadeth were quite unique, and I wanted to know what he was doing so I could incorporate that sound in my own way for my own material. So I simply learned the solos! I now understand his style, thats all there is to it.
For Rush, there should be plenty of tabs out there on the internet you can learn from. I would recommend a guitar pro/powertabs type tabulature program, thats where the good accurate tabs are.