I'm more into finding new artists than rediscovering old ones.... so heres some stuff you should check out that haven't been listed.
The Mars Volta (very Led Zeppelin/Pink Floyd'ish. John Fruscianti (sp?) plays guitar on some of the tracks.)
Eric Sardinas - Black Pearls (Slide blues player, will blow your mind)
Queens of the Stone Age - Lullabies to Paralyze
Along with those check out
The Allman Brothers (Derek Trucks and Warren Haynes... wow)
A lot of stuff has been already so theres just a few more that you should check out.