Listen to alot of them, in many different styles. May I suggest a few.

"Crossroads" Eric Clapton with Cream.

"Little Wing" Stevie Ray Vaughan

"Texas Flood" Stevie Ray Vaughan

"Cliffs of Dover" Eric Johnson

"Eruption" Eddie Van Halen

"Taxman" Paul McCartney, The Beatles, Revolver LP.

"Something" George Harrison, The Beatles, Abbey Road LP.

Probably some Yngwie in there somewhere, all the kings (B.B, Albert, Freddie), Albert Collins, Jimi Page, Hendrix, Segovia, various acoustic guitar solos..... etc.

Figure out which ones you like, why, and talk about it. :D

Peace,
-Rick