Generally, well to my ear steel strings have a sharper attack which makes the sound more defined than nylon string. Nylon strings are easier on the fingers when you are starting out but, unless you are playing classical music don't sound as clear.
Hope this helps
My instructors page and www.studiotrax.net for all things recording.
my toons Brought to you by Dr BadGAS
my toons Brought to you by Dr BadGAS