For other effects, the most important are : reverb, delay , chorus & noise gate .. and of course the most important effect after the distortion is a wah-pedal
Also you may like to have: compressors, limiters, flanger,phaser, harmonizer,whamy,vibrato,auto-wah,etc... but these aren't essential for everybody.
Anyway, I recomend a good Multi-effect, but their only disadvantage is no matter how good they are, I've never heard a good wah-pedal from a multi-effect ..