Jason Becker - Perpetual Burn
Steve Vai - Answers (G3 version with crazyass tapping solo at the end)
Jimmy Page - Bron-Yr-Aur and Fool In The Rain are sweet
Kenny Wayne Shepherd - Blue On Black
Trey Anastasio - Landlady (the interlude part of "Punch You In The Eye", Phish rarely plays this alone anymore, but listen to PYITE, it's a pretty sweetsounding guitar piece)
Brian May - Bohemian Rhapsody, Killer Queen, Hammer to Fall... all his solos rock
Richie Sambora (Bon Jovi) - "Bed of Roses" = short but sweet solo, great fretwork throughout the song...
there are SOOO many other cool ones but this is more than enough for one post. PEACE