E --3--
B --3--
G --34
D --3-5
A --3-5
E --3---
You might notice that this is an E chord shape
Proper way- hold finger nearest thumb across all strings at fret3 (daunting isn't it- i remember), put next finger at fret 4 on 3rd string, put finger 3 at fret 5 on 5th string, put your little finger at fret 5 on string 4.
Cheat- only hold down the first 2 strings with your first finger!!
Please note that i'm not brilliant at barre chords and with have been known to **** them up.
Finally .Practise,Practise,Practise or Practice,Practice,Practice - as we say over here. Try only playing barres for a short while and then go back to "ordinary chords" ,or easy to hold bits, or you will knacker your hands.
Good luck and keep,um,on keeping on.
Accuracy,you say? hmm interesting concept..