and majour scale has less feel than pentatonic. sayin this the majour scale can be used to create the pentatonic sound easily. and indeed switch between several pentatonics. ( pentatonic means 5 note scale).
personally i think it wuld be better to learn majour scale first. but it is easier to make decent soundin lead with pentatonic than diatonic (seven note ) scales eg majour.
so its up to u. if u are gonna go for the theory approach go for diatonic scale.