The advantage I can see in the m-audio black box is that it has drum loops built in, which the POD doesn't - that might be useful if you're starting out.... one less thing to worry about to get up and running.
I've never used any m-audio products, so can't say for sure how good they are - it gets good reviews though. Some people dislike the POD amp models, but with a bit of tweaking I think they are usable for home recording...
try these:
M-Audio Black Box reviews
Line 6 POD xt Reviews (Pro version - same functions though)
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